基于X射线荧光光谱法测定少量样品的主次元素     

张彩霞  孙忠 《中国沙漠》2012,32(5):1263-1267

在某些实验中,由于样品来源的有限性,导致样品数量有限,因而有必要探讨少量样品中主次元素的测定方法。X射线荧光光谱法具有样品制备简单、分析速度快、重现性好、测量范围宽和多元素同时进行分析的特点,目前在众多领域中得到了广泛的应用。基于回归曲线法、经验系数法和康普顿散射线内标法求取了各待测元素的工作曲线常数、元素间效应的影响系数和谱重叠系数,并对4 g(32 mm内径,常规)和1 g(10 mm内径,少量)样品测量的精密度和准确度进行了比较分析。结果表明,4 g(32 mm内径,常规)样品测量平均精密度约为1%,1 g(10 mm内径,少量)样品的平均精密度约为3%。测定结果基本能够满足覆盖区多目标地球化学调查样品的质量要求。  相似文献   

A neural network based methodology to predict site-specific spectral acceleration values     

Kamatchi P  Rajasankar J  Ramana GV  Nagpal AK 《地震工程与工程振动(英文版)》2010,9(4):459-472

A general neural network based methodology that has the potential to replace the computationally-intensive site-specific seismic analysis of structures is proposed in this paper. The basic framework of the methodology consists of a feed forward back propagation neural network algorithm with one hidden layer to represent the seismic potential of a region and soil amplification effects. The methodology is implemented and verified with parameters corresponding to Delhi city in India. For this purpose, strong g...  相似文献   

Study on elastic response of structures to near-fault ground motions through record decomposition   总被引：4，自引：0，他引：4  

S. Farid Ghahari  Hossein JahankhahM. Ali Ghannad 《Soil Dynamics and Earthquake Engineering》2010

Accelerograms recorded near active faults have some important characteristics that make them different from those recorded in far-fault regions. High-frequency components in acceleration records and long-period velocity pulses are among notable specifications of such ground motions. In this paper, a moving average filtering with appropriate cut-off frequency has been used to decompose the near-fault ground motions into two components having different frequency contents: first, Pulse-Type Record (PTR) that possesses long-period pulses; second, the relatively high-frequency BackGround Record (BGR), which does not include large velocity pulses. Comparing the results with those extracted through wavelet analysis shows that moving average filter is an appropriate and efficient tool for near-fault records decomposition. The method is applied to decompose a suite of 91 selected near-fault records and the elastic response of structures is examined through their response to the decomposed parts. The results emphasizes that in contrast with ordinary far-fault earthquake records, response spectra of near-fault ground motions typically have two distinct local peaks, which are representatives of the high- and low-frequency components, i.e., BGR and PTR, respectively. Moreover, a threshold period is identified below which the response of structures is dominated by BGR while PTR controls the response of structures with periods longer than this period.  相似文献   

Rapidly installed temporary gauging for hurricane waves and surge,and application to Hurricane Gustav     

Andrew B. Kennedy  Uriah Gravois  Brian Zachry  Rick Luettich  Tony Whipple  Robert Weaver  Janelle Reynolds-Fleming  Qin J. Chen  Roni Avissar 《Continental Shelf Research》2010

Hurricanes can produce extreme nearshore waves and surge, but permanent gauging stations are often much sparser than is desired. This paper describes the rationale behind and outline for rapidly installed temporary coastal gauges, and presents results during Hurricane Gustav (2008). Within 48 h prior to landfall, twenty self-recording pressure gauges were deployed in depths of 1.4–23 m over more than 700 km of coastline, using helicopters to cover the large distances. Results showed a complex picture that was strongly dependent on location. East of the Mississippi Delta, open coast waves were large, and surge reached 3.8 m NAVD88 in marshes. West of the delta but near landfall, waves and surge were generally smaller as the river levees blocked flow from East to West. West of landfall, both waves and surge were very small and the most prominent feature was a water level drawdown that reached 1.5 m. Wave spectra varied strongly depending both on location and time from landfall.  相似文献   

时变功率谱空间变化性分析     

钟菊芳  胡晓  邢义川 《地震研究》2010,33(1)

基于我国台湾地区SMART-1密集台阵强震记录资料和Kameda的时变功率谱模型,利用多重滤波技术和非线性最小二乘法拟合得到每条记录的Kameda模型参数值;通过分析模型参数随频率变化的散点图分布规律,建立了时变功率谱模型参数随频率变化的随机模型。采用随机振动理论和多元统计分析方法,分析了沿波传播方向距离、垂直于波传播方向距离及测点所在位置土层厚度等局部空间位置变化对时变功率谱模型参数的影响规律,探讨了时变功率谱模型参数的空间分布形式,建立了各模型参数随空间坐标变化的随机预测模型,从而为重大工程多点输入地震动参数的确定和多点输入加速度时程的合成提供实用模型。  相似文献   

A stochastic ground motion model with separable temporal and spectral nonstationarities     

Sanaz Rezaeian  Armen Der Kiureghian 《地震工程与结构动力学》2008,37(13):1565-1584

A fully nonstationary stochastic model for strong earthquake ground motion is developed. The model employs filtering of a discretized white‐noise process. Nonstationarity is achieved by modulating the intensity and varying the filter properties in time. The formulation has the important advantage of separating the temporal and spectral nonstationary characteristics of the process, thereby allowing flexibility and ease in modeling and parameter estimation. The model is fitted to target ground motions by matching a set of statistical characteristics, including the mean‐square intensity, the cumulative mean number of zero‐level up‐crossings and a measure of the bandwidth, all expressed as functions of time. Post‐processing by a second filter assures zero residual velocity and displacement, and improves the match to response spectral ordinates for long periods. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Measuring proton energies and fluxes using EIT (SOHO) CCD areas outside the solar disk images     

L. V. Didkovsky  D. L. Judge  A. R. Jones  E. J. Rhodes  J. B. Gurman 《Astronomische Nachrichten》2006,327(4):314-320

An indirect proton flux measuring tool based on discrimination of the energy deposited by protons in 128 × 128 pixel EIT CCD areas outside the solar disk images is presented. Single pixel intensity events are converted into proton incident energy flux using modeled energy deposition curves for angles of incidence ±60° in four EIT spatial areas with different proton stopping power. The extracted proton flux is corrected for both the loss of one‐pixel events in the range of angles of incidence as well as for the contribution to the single pixel events resulting from scattered middle‐energy protons (low‐energy or high‐energy particles are stopped by the EIT components or pass through them, accordingly). A simple geometrical approach was found and applied to correct for a non‐unique relation between the proton‐associated CCD output signal and the incident proton energy. With this geometrical approximation four unique proton incident energy ranges were determined as 45–49, 145–154, 297–335, and 390–440 MeV. The indirect proton flux measuring tool has been tested by comparing Solar Energetic Particles (SEP) flux temporal profiles extracted from the EIT CCD frames and downloaded from the GOES database for the Bastille Day (BD) of 2000 July 14 and the more recent 2005 January 20 events. The SEP flux temporal profiles and proton spectra extracted from the EIT in the relatively narrow energy ranges between 45 and 440 MeV reported here are consistent with the related GOES profiles. The four additional EIT extracted ranges provide higher energy resolution of the SEP data. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

夏季黄海、东海鞭毛虫的丰度与悬浮颗粒物的关系   总被引：7，自引：0，他引：7  

潘科  黄凌风  郭丰  黄邦钦 《海洋学报》2005,27(6):107-115

对2001年8月黄海中部和南部以及东海北部海洋鞭毛虫的丰度及其与悬浮颗粒物的数量关系进行了研究,发现调查区域内的鞭毛虫丰度为44~12 600个/cm3,它们在悬浮颗粒中所占的比例可达60%以上.悬浮颗粒物的粒径谱可以分为平缓型、驼峰型、浮游生物型和混合型.鞭毛虫丰度的变化与悬浮颗粒物的数量分布具有相似的变化趋势,整体上来说,两者数量的相关性显著,而不同的粒径谱类型中,两者的关系有不同的特点.对两者的数量关系进行了初步的探讨,并为今后海域生态调查中鞭毛虫丰度的快速估计提供一条新的途径.  相似文献   

光谱对许氏平鲉消化代谢节律及生理应激研究          下载免费PDF全文

房莹莹  陈璐璐  刘松涛  孙飞  吴燕玲  李鑫  刘鹰  马贺 《海洋科学》2023,47(10):94-111

为探究不同光谱下许氏平鲉的消化代谢水平及外周激素节律,在5种光谱(红光、绿光、黄光、蓝光、白光,光周期12L∶12D)下,通过对许氏平鲉的血清、肠道、肝脏进行24 h (8:00,12:00,16:00,20:00,24:00)取样,结果显示:不同的光谱下许氏平鲉的消化代谢酶活性除胰蛋白酶(TRY)外均具有节律性,红光、黄光下α-淀粉酶(α-AMS)、脂肪酶(LPS)活性的峰值相位与白光组相比左移;胰蛋白酶活性无时间差异性;在绿光、黄光及红光下乳酸脱氢酶(LDH)活性的峰值相位与白光组相比发生左移,在五种光谱环境中,红、黄光影响消化酶活性峰值提前出现;丙酮酸激酶(PK)活性在绿、蓝及红光下峰值相位左移;己糖激酶(HK)的活性在绿、蓝、黄光下,其峰值相位与白光组相比发生左移,在五种光谱环境中,绿、蓝光影响代谢酶活性类峰值提前出现。许氏平鲉血清中褪黑素含量呈现昼低夜高分泌水平;皮质醇的含量表现为在白天降低,午夜显著升高至最高值后又持续降低。峰值相位的改变预示着生理节律的变动,以上结果表明不同光谱可以影响鱼类的生理代谢节律,在今后养殖过程中需要充分考虑光谱对养殖生物的生物学作用,进而制定更为合理的光照条件。  相似文献   

Recent progress on anomalous X-ray pulsars     

Victoria M. Kaspi 《Astrophysics and Space Science》2007,308(1-4):1-11

I review recent observational progress on Anomalous X-ray Pulsars, with an emphasis on timing, variability, and spectra. Highlighted results include the recent timing and flux stabilization of the notoriously unstable AXP 1E 1048.1–5937, the remarkable glitches seen in two AXPs, and the newly recognized variety of AXP variability types, including outbursts, bursts, flares, and pulse profile changes. I also discuss recent discoveries regarding AXP spectra, including their surprising hard X-ray and far-infrared emission, as well as the pulsed radio emission seen in one source. Much has been learned about these enigmatic objects over the past few years, with the pace of discoveries remaining steady. However additional work on both observational and theoretical fronts is needed before we have a comprehensive understanding of AXPs and their place in the zoo of manifestations of young neutron stars.   相似文献